Terrestrial dissolved organic matter source affects disinfection by-product formation during water treatment and subsequent toxicity.

Restoring woody vegetation to riparian zones helps to protect waterways from excessive sediment and nutrient inputs. However, the associated leaf litter can be a major source of dissolved organic matter (DOM) leached into surface waters. DOM can lead to the formation of disinfection by-products (DBPs) during drinking water treatment. This study investigated the DBPs formed during chlorination of DOM leached from leaf litter and assessed the potential toxicity of DBPs generated. We compared the leachate of two native Australian riparian trees, Casuarina cunninghamiana and Eucalyptus tereticornis, and a reservoir water source from a catchment dominated by Eucalyptus species. Leachates were diluted to dissolved organic carbon concentrations equivalent to the reservoir (~9 mg L-1). E. tereticornis leachates produced more trihalomethanes (THMs), haloacetic acids (HAAs), and haloketones after chlorination, while C. cunninghamiana produced more chloral hydrate and haloacetonitriles. Leachate from both species produced less THMs and more HAAs per mole of carbon than reservoir water. This may be because reservoir water had more aromatic, humic characteristics while leaf leachates had relatively more protein-like components. Using in vitro bioassays to test the mixture effects of all chemicals, chlorinated E. tereticornis leachate induced oxidative stress in HepG2 liver cells and bacterial toxicity more frequently and at lower concentrations than C. cunninghamiana and reservoir water. Overall, this study has shown that the DOM leached from litter of these species has the potential to generate DBPs and each species has a unique DBP profile with differing bioassay responses. E. tereticornis may pose a relatively greater risk to drinking water than C. cunninghamiana as it showed greater toxicity in bioassays. This implies tree species should be considered when planning riparian zones to ensure the benefits of vegetation to waterways are not offset by unintended increased DBP production and associated toxicity following chlorination at downstream drinking water intakes.

Effects of aging of ferric-based drinking water sludge on its reactivity for sulfide and phosphate removal.

Recent studies demonstrated the practical potential of multiple beneficial reuse of ferric-rich drinking water sludge (ferric DWS) for sulfide and phosphate removal in wastewater applications. In practice, ferric DWS is often stored on-site for periods ranging from days to several weeks (or even months), which may affect its reuse potential through changes in iron speciation and morphology. In this study, we investigated for the first time the impact of ferric DWS 'aging' time on the iron speciation and morphology and its subsequent impact on its reactivity and overall sulfide and phosphate removal capacity. A series of coagulation tests were conducted to generate ferric DWS of a practically relevant composition by using raw influent water from a full-scale drinking water treatment plant (DWTP). A comparison with ferric DWS from 8 full-scale DWTPs confirmed the similitude. The presence of akaganeite (ß-FeOOH) was detected in ferric DWS (through XRD analyses), independent of the DWS storage time. However, the morphology of akaganeite changed over time from a predominant poorly-crystalline phase in 'fresh' DWS (8 ± 0.1% of total Fe) to a highly crystalline phase (76 ± 3% of total Fe) at a sludge aging time of 30 days which was confirmed by means of Rietveld refinement in XRD analyses (n = 3). Subsequent batch tests showed that its sulfide removal capacity decreased significantly from 1.30 ± 0.02 mmol S/mmol Fe (day 1) to 0.60 ± 0.01 (day 30), a decrease of 54 % (p < 0.05). The level of crystallinity however had no impact on sulfide removal kinetics, most sulfide being removed within 10 minutes. Upon aeration of sulfide-loaded ferric DWS in activate sludge, amorphous iron oxides species were formed independent of the initial DWS crystallinity which resulted in efficient P removal at capacities similar to that of conventional FeCl3 dosing.

Selective laser assisted impairment of reverse osmosis membranes.

Monitoring the loss of integrity in reverse osmosis (RO) membranes is crucial for protection of public health as small imperfections can result in catastrophic pathogen outbreaks. However, understanding the phenomena accompanying the loss of integrity in RO membranes relies on properly characterizing and interpreting performance data. Reproducing chemical and mechanical damage in model membranes that mimic the conditions of real-time operation is difficult. Mechanical impairment is particularly challenging, since one needs to damage selectively and in a controlled manner (producing holes of desired size) the barrier (polyamide) and/or the support layer (polyether sulfone and polyester). In this work we develop a straightforward approach to produce arrays of micro-holes in a commercially available RO membrane employing nanosecond pulsed laser ablation. The new approach is used to prepare four samples with different number of holes with constant diameter and increasing hole depth. These samples were further tested to reveal the impairment impact on filtration performance. It was observed that the flux was linked with the laser pulse density/penetration.•Uniform radius defects were created in RO membranes.•Higher pulse density leads to deeper defects.•Ablation of all three layers can be attained.

Removal of Pharmaceuticals and Illicit Drugs from Wastewater Due to Ferric Dosing in Sewers.

Ferric (Fe3+) salt dosing is an efficient sulfide control strategy in the sewer network, with potential for multiple benefits including phosphorus removal in the biological reactors and sulfide emission control in the anaerobic digesters of wastewater treatment plant (WWTP). This paper extends the knowledge on the benefit of iron dosing by exploring its impact on the fate of organic micropollutants (MPs) in the wastewater using sewer reactors simulating a rising main sewer pipe. The sulfide produced by the sewer biofilms reacted with Fe3+ forming black colored iron sulfide (FeS). Among the selected MPs, morphine, methadone, and atenolol had >90% initial rapid removal within 5 min of ferric dosing in the sewer reactor. The ultimate removal after 6 h of retention time in the reactor reached 93-97%. Other compounds, ketamine, codeine, carbamazepine, and acesulfame had 30-70% concentration decrease. The ultimate removal varied between 35 and 70% depending on the biodegradability of those MPs. In contrast, paracetamol had no initial removal. The rapid removal of MPs was likely due to adsorption to the FeS surface, which is further confirmed by batch tests with different FeS concentrations. The results showed a direct relationship between the removal of MPs and FeS concentration. The transformation kinetics of these compounds in the reactor without Fe3+ dosing is in good agreement with biodegradation associated with the sewer biofilms in the reactor. This study revealed a significant additional benefit of dosing ferric salts in sewers, that is, the removal of MPs before the sewage enters the WWTP.

Effective removal of MIB and geosmin using MBBR for drinking water treatment.

Biodegradation is an effective method for the removal of taste and odour (T&O) compounds from drinking water sources. In this study, the applicability of a moving-bed biofilm reactor (MBBR) as biological treatment step for the control of MIB and geosmin was studied at pilot-scale. After a 3.5 month acclimation period both T&O compounds could be reliably removed by at least 80%. Biodegradation was found to be the dominant removal mechanism with air stripping contributing up to 25% at shorter HRTs. Also sorption of MIB and geosmin onto carriers and biofilm did occur, simultaneously facilitating the biodegradation process. The biodegradation of MIB and geosmin followed pseudo-first-order kinetics.

Factors affecting the formation of disinfection by-products during chlorination and chloramination of secondary effluent for the production of high quality recycled water.

During the production of high quality recycled water by reverse osmosis membrane filtration secondary effluent must be disinfected to limit biofouling on the membrane surface. Advanced Water Treatment Plants in South East Queensland, Australia use disinfectant contact times ranging from 30 min up to 24 h. Disinfectants such as chlorine and chloramines react with effluent organic matter to generate disinfection by-products (DBPs) which could be potentially hazardous to human health if the water is destined for supplementing public water supplies. In this context, secondary effluents are of concern because of their high total organic carbon content which can act as DBP precursors. Also, effluent organic matter may form different DBPs to those formed from natural organic matter during conventional drinking water treatment, either in quantity, identity or simply in the abundance of different DBPs relative to each other. It cannot be assumed per se with certainty that DBP formation will be affected in the same way by operational changes as in drinking water production. Response surface modelling has been employed in this study at the bench scale to investigate the effect of reaction time (0-24 h), pH (5.5-8.5), temperature (23-35 °C), disinfection strategy (chlorine vs chloramines used prior to membrane treatment) and the interaction between these different parameters on DBP formation during disinfection of secondary effluent. The concentration of halogenated DBPs formed during the first 24 h of reaction with the different disinfectants followed the order chlorination >> in line-formed monochloramine > pre-formed monochloramine. Contact time with chlorine was the major influencing factor on DBP formation during chlorination, except for the bromine-containing trihalomethanes and dibromoacetonitrile for which pH was more significant. Chlorination at high pH led to an increased formation of chloral hydrate, trichloronitromethane, dibromoacetonitrile and the four trihalomethanes while the opposite effect was observed for the other targeted DBPs. Temperature was identified as the least influencing parameter compared to pH and reaction time for all DBPs in all the disinfection strategies, except for the formation of chloral hydrate where pH and temperature had a similar significance and bromoform that was similarly affected by temperature and reaction time. Chloramines employed at pH 8.5 reduced the concentration of all studied DBPs compared to pH 5.5. Furthermore, reaction time was the most significant factor for trichloronitromethane, chloroform, trichloroacetonitrile, dichloroacetonitrile and bromochloroacetonitrile formation while pH was the most influencing factor affecting the formation of the remaining DBPs.